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Catalog Service:
Millimeter wave spectrum of methyl cyanate

Short name: J/A+A/591/A75
IVOA Identifier: ivo://CDS.VizieR/J/A+A/591/A75
DOI (Digital Object Identifier): 10.26093/cds/vizier.35910075
Publisher: CDS[+][Pub. ID]
More Info: https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/591/A75
VO Compliance: Level 2: This is a VO-compliant resource.
Status: active
Registered: 2016 Jun 17 08:05:40Z
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Description


The recent discovery of methyl isocyanate (CH_3_NCO) in Sgr B2(N) and Orion KL makes methyl cyanate (CH_3_OCN) a potential molecule in the interstellar medium. The aim of this work is to fulfill the first requirement for its unequivocal identification in space, i.e. the availability of transition frequencies with high accuracy. The room-temperature rotational spectrum of methyl cyanate was recorded in the millimeter wave domain from 130 to 350GHz. All rotational transitions revealed A-E splitting owing to methyl internal rotation and were globally analyzed using the ERHAM program. The data set for the ground torsional state of methyl cyanate exceeds 700 transitions within J"=10-35 and K"a=0-13 and newly derived spectroscopic constants reproduce the spectrum close to the experimental uncertainty. Spectral features of methyl cyanate were then searched for in Orion KL, Sgr B2(N), B1-b, and TMC-1 molecular clouds. Upper limits to the column density of methyl cyanate are provided.

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Developed with the support of the National Science Foundation
under Cooperative Agreement AST0122449 with the Johns Hopkins University
The NAVO project is a member of the International Virtual Observatory Alliance

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