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Description
W Aql is an asymptotic giant branch (AGB) star with an atmospheric elemental abundance ratio C/O~=0.98. It has previously been reported to have circumstellar molecular abundances intermediate between those of M-type and C-type AGB stars, which respectively have C/O<1 and C/O>1. This intermediate status is considered typical for S-type stars, although our understanding of the chemical content of their circumstellar envelopes is currently rather limited. We wish to assess the reported intermediate status of W Aql by analysing the line emission of molecules that have not been observed towards this star before. We have performed observations in the frequency range 159-268GHz with the SEPIA/B5 and PI230 instruments on the APEX telescope. We make abundance estimates through direct comparison to available spectra towards a number of well-studied AGB stars and based on rotational diagram analysis in the case of one molecule. From a compilation of our abundance estimates and those found in the literature for two M-type (R Dor, IK Tau), two S-type ({chi} Cyg, W Aql), and two C-type stars (V Aql, IRC +10 216), we conclude that W Aql's circumstellar environment appears considerably closer to that of a C-type AGB star than to that of an M-type AGB star. In particular, we detect emission from C_2_H, SiC_2_, SiN, and HC_3_N, molecules previously only detected towards the circumstellar environment of C-type stars. This conclusion, based on the chemistry of the gaseous component of the circumstellar environment, is further supported by reports in the literature on the presence of atmospheric molecular bands and spectral features of dust species which are typical for C-type AGB stars. Although our observations mainly trace species in the outer regions of the circumstellar environment, our conclusion matches closely that based on recent chemical equilibrium models for the inner wind of S-type stars: the atmospheric and circumstellar chemistry of S-type stars likely resembles that of C-type AGB stars much more closely than that of M-type AGB stars. Further observational investigation of the gaseous circumstellar chemistry of S-type stars is required to characterise its dependence on the atmospheric C/O. Non-equilibrium chemical models of the circumstellar environment of AGB stars need to address the particular class of S-type stars and the chemical variety that is induced by the range in atmospheric C/O.
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