Description
The spectrum of CoIII has been recorded in the region 1562-2564{AA} (64000cm^-1^-39000cm^-1^) by Fourier transform (FT) spectroscopy, and in the region 1317-2500{AA} (164000cm^-1^-40000cm^-1^) using a 10.7m grating spectrograph with phosphor image plate detectors. The spectrum was excited in a cobalt-neon Penning discharge lamp. We classified 514 CoIII lines measured using FT spectroscopy, the strongest having wavenumber uncertainties approaching 0.004cm^-1^ (approximately 0.2m{AA} at 2000{AA}, or 1 part in 10^7^), and 240 lines measured with grating spectroscopy with uncertainties between 5 and 10m{AA}. The wavelength calibration of 790 lines of Raassen & Orti Ortin (1984PhyBC.123..353R) and 87 lines from Shenstone (1960CaJPh..38..677S) has been revised and combined with our measurements to optimize the values of all but one of the 288 previously reported energy levels. Order of magnitude reductions in uncertainty for almost two-thirds of the 3d^6^4s and almost half of the 3d^6^4p revised energy levels are obtained. Ritz wavelengths have been calculated for an additional 100 forbidden lines. Eigenvector percentage compositions for the energy levels and predicted oscillator strengths have been calculated using the Cowan code.
|